Difference between revisions of "Emission factors for burning processes"

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Buildings need to be heated in winter so Combined Heat and Power (CHP) plants are placed to cities close to humans. Emissions have health impacts locally and globally.

Question

What are the emission factors for burning processes in Finland? Emission factors are estimated in Finland and kettle/plant types used in Finland only.

Answer

⇤# : Rcode for getting the ovariable is missing. --Jouni 22:05, 26 February 2013 (EET)

Rationale

Inputs

See discussions with the statements in the discussion page.D↷

**Variables in the assessment model**
Ovariable	Dependencies	Measure	Indices
emissions (from the model) (emissions in mass per time):	energyUse (from Energy use of buildings or other relevant source)
	fuelShares (fairly generic knowledge from e.g. Energy balance in Kuopio --# : Currently this data is on page Emission factors for burning processes Table Fuel use in different heating types. However, this is clearly case-specific data and should be on a case-specific page. This should be done retrospectively to Kuopio and Basel as well. --Jouni (talk) 09:22, 24 May 2015 (UTC)	Tells how much of fuel is used for a certain neating energy need.	Required indices: Fuel_type. Typical indices:
	emissionFactors (generic information, but may be cultural differences. E.g. Emission factors for burning processes ##	emissions per unit of energy produced (g / J or similar unit)	Required indices: Exposure_agent. Typical indices: Emission_height.

Calculations

+ Show code - Hide code

###This code is Op_en2791/emissions on page [[Emission factors for burning processes]].

library(OpasnetUtils)

####### Calculate emissions

emissions <- Ovariable("emissions", 
	dependencies = data.frame(
		Name = c(
			"energyUse",
			"fuelShares", 
			"emissionFactors",
			"emissionLocations"
		),
		Ident = c(
			NA, # typically from [[Energy use of buildings]] but there are two ways to calculate
			NA, # case-specific
			"Op_en2791/emissionFactors", # [[Emission factors for burning processes]]
			NA
		)
	),
	formula = function(...) {

		out <- oapply(energyUse, cols = c("Building", "Efficiency"), FUN = sum)
		out <- out * fuelShares * emissionFactors * 3.6  * 1E-9 # convert from kWh /a to MJ /a and mg to ton

		if(!"City_area" %in% colnames(out@output)) {
			out <- out * Ovariable(
				output = data.frame(City_area = "Not known", Result = 1),
				marginal = c(TRUE, FALSE)
			)
		}
		out <- unkeep(out * emissionLocations, sources = TRUE, prevresults = TRUE)
	
		out@output$Emission_site <- as.factor(ifelse(
			out@output$Emission_site == "At site of consumption",
			as.character(out@output$City_area),
			as.character(out@output$Emission_site)
		))

		out <- oapply(
			out,
			cols = c("Burner", "City_area"),
			FUN = sum
		)
		return(out)
	}
)

objects.store(emissions)
cat("Ovariable emissions stored.\n")

Emission factors for heating

This data are used in Urgenche.

Emission factors for wood heating(PJ /a; mg /MJ)
Obs	Type	Activity in Finland	PM2.5 emission factor	Description
1	Residential buildings	34.2 (30.8-37.6)		Karvosenoja et al. 2008
2	Primary wood-heated residential buildings	20.2 (16.6-23.9)		Karvosenoja et al. 2008
3	Manual feed boilers with accumulator tank	5.42 (3.89-7.22)	80.0 (37.6-150)	Karvosenoja et al. 2008
4	Manual feed boilers without accumulator tank	2.67 (1.67-3.87)	700 (329-1310)	Karvosenoja et al. 2008
5	Automatic feed wood chip boilers	1.46 (1.01-2)	50.0 (23.5-93.9)	Karvosenoja et al. 2008
6	Automatic feed pellet boilers	0.102 (0.0693-0.142)	30.0 (14.1-56.3)	Karvosenoja et al. 2008
7	Iron stoves	0.142 (0.0976-0.196)	700 (329-1310)	Karvosenoja et al. 2008
8	Other stoves and ovens	10.2 (7.86-12.8)	140 (65.8-263)	Karvosenoja et al. 2008
9	Low-emission stoves	0	80 (37.6-150)	Karvosenoja et al. 2008
10	Open fireplaces	0.163 (0.111-0.224)	800 (376-1500)	Karvosenoja et al. 2008
11	Supplementary wood-heated residential buildings	14.0 (10.7-17.4)		Karvosenoja et al. 2008
12	Iron stoves	0.212 (0.135-0.316)	700 (329-1310)	Karvosenoja et al. 2008
13	Other stoves and ovens	13.6 (10.4-16.9)	140 (65.8-263)	Karvosenoja et al. 2008
14	Low-emission stoves	0	80 (37.6-150)	Karvosenoja et al. 2008
15	Open fireplaces	0.222 (0.14-0.332)	800 (376-1500)	Karvosenoja et al. 2008
16	Recreational buildings	5.00 (4.50-5.50)		Karvosenoja et al. 2008
17	Iron stoves	0.782 (0.372-1.37)	700 (329-1310)	Karvosenoja et al. 2008
18	Other stoves and ovens	3.96 (3.19-4.59)	140 (65.8-263)	Karvosenoja et al. 2008
19	Open fireplaces	0.262 (0.118-0.477)	800 (376-1500)	Karvosenoja et al. 2008

Karvosenoja et al. 2008 ^[1]

The table below contains the current situation for Kuopio and Basel and Helsinki. Kuopio uses 'District', and Basel uses 'Long-distance heating', and Helsinki uses 'District heating'.

Fuel use in different heating types(-)
Obs	Heating	Burner	Fuel	Fraction	Description
1	Wood	Domestic	Wood	1
2	Oil	Domestic	Light oil	1
3	Gas	Domestic	Gas	1
4	Heating oil	Domestic	Light oil	1
5	Other sources	Domestic	Other sources	1
6	No energy source	Domestic	Other sources	1
7	Geothermal	Grid	Electricity	0.3	Geothermal does not sum up to 1 because more heat is produced than electricity consumed.
8	Centrifuge, hydro-extractor	Grid	Electricity	0.3	Not quite clear what this is but presumably a heat pump.
9	Solar heater/ collector	Grid	Electricity	0.1	Use only; life-cycle impacts omitted.
10	Electricity	Grid	Electricity	1

+ Show code - Hide code


# This is code Op_en2791/fuelSharesgeneric (only generic) on page [[Emission factors for burning processes]].
library(OpasnetUtils)

fuelSharesgeneric <- Ovariable("fuelSharesgeneric", ddata = "Op_en2791", subset = "Fuel use in different heating types")
colnames(fuelSharesgeneric@data) <- gsub("[ \\.]", "_", colnames(fuelSharesgeneric@data))
#fuelSharesgeneric@data <- merge(fuelSharesgeneric@data, data.frame(Time = 1900:2080))

objects.store(fuelSharesgeneric)
cat("Objects fuelSharesgeneric initiated!\n")

⇤# : District heating moved out of the generic table. Should be put to city-specific pages. --Jouni (talk) 04:41, 12 June 2015 (UTC)

For guesstimates about Long-distance heating (which is used in Basel), see Climate change policies in Basel and de:IWB.

Emission factors of energy production(mg /MJ)
Obs	Burner	Fuel	PM2.5	CO2	CO2official	CO2-eq	Description
1	Domestic	Wood	140 (65.8-263)	74200	0	8333	Other stoves and ovens. Karvosenoja et al. 2008
2	Domestic	Light oil	0-10	74200-87222	74200	87222	Light oil <5 MW Emission factors for burning processes. Light oil 267 kg /MWh
3	Domestic	Other sources	0-10	74200	74200		Same as oil.
4	Domestic	Gas	0-3	55650	55650		For PM2.5: one third of that of oil. For CO2: 3/4 of that of oil.
5	Large fluidized bed	Gas	0-3	55650	55650		For PM2.5: one third of that of oil. For CO2: 3/4 of that of oil.
6	Large fluidized bed	Coal	2-20	106000	106000		Same as peat.
7	Large fluidized bed	Wood	2-20	74200	0		Leijupoltto 100-300 MW Emission factors for burning processes. Karvosenoja et al., 2008
8	Large fluidized bed	Waste	2-20	74200	0		Same as wood
9	Large fluidized bed	Peat	2-20	106000	106000		Leijupoltto 100-300 MW Emission factors for burning processes. Peat 382 kg /MWh
10	Large fluidized bed	Heavy oil	8-22	91111-106000	106000	91111	Leijupoltto 100-300 MW Emission factors for burning processes. Peat 382 kg /MWh
11	Grid	Electricity	1-10	53000	212000		50 % of large-scale burning (because of nuclear and hydro). Heavy oil 279 kg /MWh. Officially, electricity is not CHP but requires a double amount of coal to produce it.

EKOREM: Sähkölämmitys ja lämpöpumput sähkönkäyttäjinä ja päästöjen aiheuttajina Suomessa, some values (all CO2-eq) taken from here.

Sanni Väisänen: Greenhouse gas emissions from peat and biomass-derived fuels, electricity and heat — Estimation of various production chains by using LCA methodology --# : This work should be carefully read. It may affect values. --Jouni (talk) 13:27, 20 March 2014 (EET)

In Finland there are about 700 kettles that has under 5MW fuel power. Same amount is between 5 to 50 MW kettles and over 50 MW kettles there are 200 in Finland. One heating power plant can have several kettles. Many 5-50 MW power plants has also less than 5 MW kettle. ^[2]

+ Show code - Hide code


# This is code Op_en2791/emissionFactors on page [[Emission factors for burning processes]].
library(OpasnetUtils)

emissionFactors <- Ovariable(
	name = 'emissionFactors',
	ddata = 'Op_en2791', # [[Emission factors for burning processes]]
	subset = 'Emission factors of energy production'
)

objects.store(emissionFactors)
cat("Objects emissionFactors initiated!\n")

Other data

Show details

Table 1. Describing emission types in different kind of plants and kettles with different fuels and fuel power.

Difference between revisions of "Emission factors for burning processes"(kg /MWh or mg /MJ)
Obs	Type of plant or kettle	Fuel power (MW)	Fuel	Emission type	PM separator	Unit	Result	Description
1	-	-	Heavy oil	CO2	-	kg /MWh	279	-
2	Poltinpoltto	<5	Heavy oil	PM	partly syklone	mg /MJ	20-90	Number of plants: 300
3	Poltinpoltto	5-15	Heavy oil	PM	partly syklone	mg /MJ	10-70	200
4	Poltinpoltto	15-50	Heavy oil	PM	partly syklone	mg /MJ	5-40	100
5	-	>50	Heavy oil	TSP	-	mg /MJ	15 (5-30)	Savolahti M., Personal communication
6	-	>50	Heavy oil	PM2.5	-	mg /MJ	5 (1.5-9)	Savolahti M., Personal communication
7	-	-	Light oil	CO2	-	kg /MWh	267	-
8	Poltinpoltto	<5	Light oil	PM	-	mg /MJ	0-10	20
9	Poltinpoltto	5-15	Light oil	PM	-	mg /MJ	0-10	20
10	Poltinpoltto	15-50	Light oil	PM	-	mg /MJ	0-10	10
11	Diesel/kaasumoottori	20-40	Heavy oil	PM	-	mg /MJ	30-60	2
12	-	-	Wood	CO2	-	kg /MWh	0	-
13	Kerrosleijukattila	5-10	Wood	PM	electric	mg /MJ	10-70	8
14	Kerrosleijukattila	10-50	Wood	PM	electric	mg /MJ	5-30	10
15	Kiertoleijukattila	5-10	Wood	PM	electric	mg /MJ	5-30	4
16	Puuarinakattila	<5	Wood	PM	syklone/electric	mg /MJ	20-150	120
17	Puuarinakattila	5-10	Wood	PM	syklone/electric	mg /MJ	20-150	50
18	Puuarinakattila	10-50	Wood	PM	syklone/electric	mg /MJ	10-150	35
19	Kaasutuskattila	2-7	Wood	PM	syklone	mg /MJ	50-150	5
20	Leijupoltto	20-100	Wood	PM2.5	(multisyklone+) electric	mg /MJ	2-20	Reference: VTT 2005
21	Leijupoltto	20-100	Biomass	PM2.5	(multisyklone+) electric	mg /MJ	2-20	Reference: VTT 2005;wood > biomass
22	Leijupoltto	100-300	Wood	PM2.5	(multisyklone+) electric	mg /MJ	1-15	VTT 2005
23	-	-	Peat	CO2	-	kg /MWh	382	-
24	Leijupoltto	5-20	Peat	PM2.5	(multisyklone+) electric	mg /MJ	5-25	VTT 2005
25	Leijupoltto	20-100	Peat	PM2.5	(multisyklone+) electric	mg /MJ	4-23	VTT 2005
26	Leijupoltto	100-300	Peat	PM2.5	(multisyklone+) electric	mg /MJ	2-20	VTT 2005
27	Leijupoltto	300-500	Peat	PM2.5	electric	mg /MJ	2-15	VTT 2005
28	Leijupoltto	>500	Peat	PM2.5	electric	mg /MJ	2	VTT 2005
29		5-20	Heavy oil	PM2.5	-	mg /MJ	4-38	VTT 2005
30		20-100	Heavy oil	PM2.5	-	mg /MJ	8-53	VTT 2005
31		20-100	Heavy oil	PM2.5	cyclone/multicyclone	mg /MJ	5-24	VTT 2005
32		100-300	Heavy oil	PM2.5	-	mg /MJ	8-22	VTT 2005
33		100-300	Heavy oil	PM2.5	cyclone/multicyclone	mg /MJ	4-13	VTT 2005

VTT 2005 ^[3]

Emission factors vary greatly depending on kettle or plant type, fuel type and fuel power. Type of emission and possible PM separator also affect to EF number.

Data been used in this page is from many different study and sources to get wide data base for EF caculations.

Emission factors from Matti's conceptual model

This data comes from File:UrgencheConceptualModel.xlsx.

Table 2.

**Emission factors (t/TJt)**
		CO2 (+CO)	CH4	BC	Fine PM	SO2	NO
Power plant/industry scale	Coal	101	0.001	0.02	5	0.7	0.3
Power plant/industry scale	Oil (residual)	82	0.003	0.02	0.01	0.5	0.1
Power plant/industry scale	NatGas	59	0.001	0.005	0	0	0.06
Power plant/industry scale	Biomass (ww+agr)	130	0.025	0.05	1	0	0.2
Power plant/industry scale	Municipal waste	100	0.029	0.05	1	0	0.2
Local heating	Coal	103	0.301	14	8	1	0.1
Local heating	Oil (distillate)	78	0.010	0.2	0	0.5	0.04
Local heating	NatGas	59	0.005	0.01	0	0	0.02
Local heating	Biomass (wood)	148	0.253	10	1	0	0.7
Transport	Petrol	67	0.001		0.01
Transport	Diesel	69	0.001		0.028	EURO-III (CRT traps)
Transport	LNG	70	0.001		0.007
Transport	Liq biofuel	64	0.010		0.03

Table 3.

**Energy contents**
C2H5OH	29.700	MJ/kg
C2	24.000	molecular weight
H6	6.000	molecular weight
O	16.000	molecular weight
Petrol	43	MJ/kg
Diesel	45	MJ/kg
Liquefied natural gas (LNG)	56	MJ/kg
Gas	49,00	MJ/kg
Solid biofuel	7,00	MJ/kg
Liquid biofuel	29,00	MJ/kg
Coal	25,60	MJ/kg
Crude oil	43,0	MJ/kg
1 kg ethanol =	0.522	kg C
produces	1.913	kg CO2
1MJ ethanol produces	0.064	kg CO2

Table 4.

**Sulphur contents**
	%
Coal S	1
Residual oil S	2.5
Distillate oil S	0.5
Diesel S	0.1
Petrol S	0.05

Table x

This data comes from File:Energy supply in Europe.xls.

**Fuel ash and sulfur contents of fuels (%)**
Fuel	Ash	Sulfur
Coal and peat	11,0	1,1
Crude oil	0,4	2,5
Petrochem products	0,04	1,5
Biofuel and waste	0,5	-

Table 5.

This data comes from File:Energy supply in Europe.xls.

**Removal rates (%)**
	Coal and peat	Petrochem products	Biofuel and waste
Power generation fly ash removal	99,5	90,0	99,0
Heat/power fly ash removal	99,5	90,0	95,0
District heating fly ash removal	95	90	90
Power generation SO2 removal	45	45
Heat/power SO2 removal	0
District heating SO2 removal	0
Power generation NOx removal	0
Heat/power NOx removal	0
District heating NOx removal	0

Table X

This data comes from File:Energy supply in Europe.xls.

**CO₂ emissions from combustion (MtCO₂/Mtoe)**
Coal & peat	Crude oil	Oil	Gas	Biofuels & waste
3,86	3,13	3,13	2,27	4,79

Table X

This data comes from File:Energy supply in Europe.xls.

**EC+OC emission factor (t/Mtoe)**
Type of plant	Coal & peat	Crude oil	Petrochem products	Gas	Biofuels & waste
Electricity plants	260		300	170	300
CHP Plants	610		400	240	800
Heat plants	1000		600	400	3000
Blast furnaces	3000
Gas works	3000	1000		100
Oil refineries		400	200	100
Petrochemical plants	1000	300
Coke/pat. fuel/BKB plants	600
Liquefication plants	600

Table 6.

**Energy efficiencies**
Fuel	Power only	CHP Power	CHP Heat	Heat only
Nuclear	0.37	0.32	0.50	1.00
Hydro
Wind, solar, geothermal
Coal/peat	0.45	0.35	0.55	0.90
Crude oil	0.50	0.40	0.50	0.90
Natural gas	0.53	0.40	0.50	0.90
Biomass	0.40	0.33	0.55	0.90
Municipal waste	0.40	0.33	0.55	0.90

Table 7.

**Relative GHG potency**
Time	CO2	CH4
20 a.	1	72
100 a.	1	25

Emission factors for PM

Table 8. Emission factors for small power plants in Finland.^[4]

Type of plant or kettle	Fuel power (MW)	Fuel	PM separator	Emission factor (mg/MJ)	Number of plants
Poltinpoltto	<5	Heavy oil	partly syklone	20-90	300
Poltinpoltto	5-15	Heavy oil	partly syklone	10-70	200
Poltinpoltto	15-50	Heavy oil	partly syklone	5-40	100
Poltinpoltto	<5	Light oil	-	<10	20
Poltinpoltto	5-15	Light oil	-	<10	20
Poltinpoltto	15-50	Light oil	-	<10	10
Diesel/kaasumoottori	20-40	Heavy oil	-	30-60	2
Kerrosleijukattila	5-10	Wood	electric	10-70	8
Kerrosleijukattila	10-50	Wood	electric	5-30	10
Kiertoleijukattila	20-40	Wood	electric	5-30	4
Puuarinakattila	<5	Wood	syklone/electric	20-150	120
Puuarinakattila	5-10	Wood	syklone/electric	20-150	50
Puuarinakattila	10-50	Wood	syklone/electric	10-150	35
Kaasutuskattila	2-7	Wood	syklone	50-150	5

("Taulukoissa esitetyt ominaispäästökertoimet edustavat vaihteluväliä, joiden sisällä suurin osa yksittäisten laitosten arvoista on. Vaihteluvälit perustuvat käytettävissä olevien laitostietokantojen arvoihin (VAHTI-tiedot) ja pienten polttolaitosten päästömittaustuloksiin.")

⇤# : Using two languages is not suitable. --Sami Rissanen 11:37, 4 February 2013 (EET)

Table 9. Emission factors for wood burning in small scale heating (e.g. secondary heating at houses) can be found from PUPO emission and toxicity database

**Table. Emissions of wood burning in different fireplaces.[3]**
Fire place	Number of measurements	Mean (mg/MJ)	Min (mg/MJ)	Max (mg/MJ)
Panospoltto	32	76	14.15	224.27
Varaava tulisija	22	80	27.97	224.27
-Perinteinen	18	91	30.75	224.27
-Moderni	3	32	27.97	36.52
Kamiinat ja muut	5	54	45.8	74.2
Kiukaat	1	168	-	-
Klapikattilat	4	59	14.15	106.14
-Perinteinen	2	102	98.59	106.14
-Moderni	2	16	14.15	17.58
Poltinpoltto	49	20	5.21	89.2
Pellettipoltin	21	21	5.21	89.2
Stokeripoltin	5	15	12.21	18.71

Emission factors for greenhousegases

EFs by fuel based classification

Heljo & Laineen selvityksessä on päädytty seuraaviin kasvihuonekaasupäästökertoimiin (kgCO2/MWh) laskettuna rakennuksen bruttotasolla (rakennukseen hankittu energia)[4]

Table 10.

kgCO2/MWh)
Puu	18
Kevyt polttoöljy	265
Raskas polttoöljy	179
Kaukolämpö, erillistuotanto	231
Kaukolämpö, yhteistuotanto	224
Kaukolämpö keskimäärin (yhteistuotantoa 73 %)	226
Sähkö keskimäärin	204
Sähkön marginaalikulutus	714
Sähkön perustehoalueen kulutus	112
Sähkön välitehoalueen kulutus	459
Sähkön huipputehoalueen kulutus	867
Sähkölämmityksen lämmitysenergia (esimerkkiarvo)	400

Table 11. Fuel classification and emission factors in Finland 2010. ^[5] ^[6]. Definitions for classification of fuels and energy sources can be found here.

Code Heading		Fuel-specific unit	CO₂ default emission factor [t/TJ]		Default net calorific value (as fired) [GJ/unit]		NB
1	Fossil fuels
11	Petroleum products
111	Petroleum gases
1111	Refinery gas	t	54.2	*	49.7	*
1112	LPG (Liquefied petroleum gas)	t	65.0		46.2
112	Light distillates
1121	Naphtha	t	72.7		44.3
1122	Motor gasoline	t	72.9		43.0
1123	Aviation gasoline	t	71.3		43.7
113	Medium distillates
1131	Kerosene (jet fuel)	t	73.2		43.3
1132	Other kerosenes	t	71.5	*	43.1
1133	Diesel oil	t	73.6		42.8
1134	Light fuel oil (heating fuel oil)	t	74.1		42.7
1135	Gasoil (for non-road use)	t	73.6	*	42.8
1139	Other medium distillates	t	74.1		42.7
114	Heavy distillates
1141	Heavy fuel oil, sulphur content < 1%	t	78.8		41.1
1142	Heavy fuel oil, sulphur content ≥ 1%	t	78.8		40.5
1143	Other heavy distillates	t	79.2	*	40.2
115	Petroleum coke	t	97.0		33.5
116	Recycled and waste oils	t	78.8		41.0
119	Other petroleum products	t	78.8		30.0
12	Coal
121	Hard coal
1211	Anthracite	t	98.3	*	33.5
1212	Hard coal, bituminous	t	94.6		24.6	*
122	Other coal
1221	Semi-bituminous coal, brown coal, lignite	t	108.0		20.0
1222	Coal briquettes	t	94.6	*	30.0
1228	Coal tar	t	90.6	*	37.0
1229	Other non-specified coal	t	108.0		10.0
123	Coke	t	108.0		29.3
124	Coke oven gas	1000 m3	41.5		16.7
125	Blast furnace gas	1000 m3	263.7		3.8
13	Natural gas
131	Natural gas	1000 m3	55.04		36.0
2	Peat
21	Peat
211	Milled peat	t	105.9		10.1
212	Sod peat	t	102.0		12.3
213	Peat pellets and briquettes	t	97.0		18.0	*
3	Renewable and mixed fuels
31	Biomass
311	Forest fuelwood
3111	Firewood (stems and split firewood)	t	109,6		14.0	*	BIO
3112	Chips from roundwood	t	109,6		9.5	*	BIO
3113	Forest residue chips	t	109,6		9.0	*	BIO
312	Industrial wood residue						BIO
3121	Bark	t	109,6		7.5	*	BIO
3122	Sawdust, cutter shavings etc.	t	109,6		8.0	*	BIO
3123	Wood residue chips	t	109,6		9.5	*	BIO
3128	Unspecified industrial wood residue	t	109,6		7.5	*	BIO
3129	Other industrial wood residue	t	109,6	*	8.8	*	BIO
313	Black liquor and other concentrated liquors	tka	109,6		11.5	*	BIO
314	Other by-products from wood processing	TJ	109,6				BIO
industry
315	Recovered wood	t	109,6		12.0	*	BIO
316	Wood pellets and briquettes	t	109,6		16.0		BIO
317	Vegetable-based fuels
3171	NEW!!Reed canary grass	t	100.0		14.6		BIO
3172	NEW!!Cereal crops and straw parts	t	109,6		13.5		BIO
3179	NEW!! Other vegetable-based fuels	t	109,6		15.0		BIO
318	Animal-based fuels	t	109.6		30.0	*	BIO
32	Other biofuels and mixed fuels
321	Biogas
3211	Landfill gas	1000 m3	56,1		17.0	*	BIO
3212	Biogas from wastewater treatment	1000 m3	56.1		23.0	*	BIO
3213	Industrial biogas	1000 m3	56.1		20.0	*	BIO
3219	Other biogas	1000 m3	56.1		20.0	*	BIO
322	Liquid biofuels	t	77.4		30..40		BIO
323	Mixed fuels (fossil and non-fossil)
3231	Recovered fuels	t	31.8		20.0		1)
3232	Demolition wood	t	17.0		15.0		1)
3233	Impregnated wood (chemically treated)	t	11.4		12.0		1)
3234	NEW!! Deinking sludge	t	60.0		4.0		1)
3238	NEW!!Municipal waste (unsorted)	t	40.0		10.0		1)
3239	Other mixed fuels	t	110.0		10.0
324	Gasified waste (Product gas)	1000 m3	..		..		2)
325	NEW!!Biosludge	t	109.6		2.5		BIO
4	Other energy sources
41	Nuclear energy
411	Nuclear energy	TJ	–
49	Others
491	Other by-products and wastes used as fuels
4911	Plastics waste	t	74.1		33.0
4912	Rubber waste	t	90.0		33.0
4913	Hazardous waste	t	117.0	*	10.0	*
4919	Other waste	t	75.0		15.0	*
492	Exothermic heat from industry	TJ	–
493	Secondary heat from industry	TJ	–
494	Electricity	MWh	–
495	Steam	MWh	–
497	NEW!!Sulphur	t	0.0		10.5
498	Hydrogen	1000 m3	0.0		10.8
499	Other non-specified energy sources	TJ	..

NB

BIO = biofuel, whose carbon dioxide emissions are not counted in the total emission amounts of Finland's greenhouse gases, nor are they taken into account in emissions trading.

1) CO₂ factor of mixed fuels is an estimate taking into account only the share of fossil carbon.

2) Gasified waste (Product gas) is reported in the fuel categories of the source materials of gasification.

Calorific values and emission coefficients describe the properties of fuel as fired, inclusive of moisture content (except for 313, where the measurement unit is tonnes of dry matter). Calorific value of natural gas has been specified in normal conditions (0 °C and 1.013 bar).

Emission factors are updated when necessary.

(* Revised values.

Emission factors for district heating is calculated in Motiva CO₂ emission calculation introductions^[7]. For district heating joint production emission factor is 220 kg CO₂/MWh. In this view other GHGs (CH₄ or N₂O) are not taken account as CO₂-ekv! Emission factors by fuel based on Motiva knowledge is in table 2.

Table 12. Emission factors of CO₂ by fuel^[8].

Fuels	kg CO₂/MWh
Heavy oil	279
Light oil	267
Gas	202
Fluid gas	227
Peat	382
Coal	341
Coke	389
Wood	0

CO2 EF for electricity can be classified in two categories: purchase electricity and own production. EF for purchase electricity is the same as own electricity vendor has informed or average Finnish electricity procurement CO2 EF (= 200 kg CO2/MWh). EF for own electricity production can be used EF from table 2 (fuel based EFs). If electricity is produced in combined electricity, heating production EFs are calculated with “benefit division method”. Method is explained in Motiva introduction^[9] (attachment 2).

Table 13. Average emission factors measured with differed gas analyzator (kk) and FTIR analyzator ^[10].

	Ordinary combustion	Distribution (%)	Bad combustion	Distribution (%)	Unit
Temperature of gas	253	1	159	17	Celsius
CO2 (kk)	7.3	5	11	8	%, dry
O2 (kk)	13.3	3	8.7	14	%, dry
H2O (FTIR)	6.5	4	7.7	-	%, wet
CO (kk)	2300	10	8100	29	mg/MJ
CO (FTIR)	2000	11	5700	-	mg/MJ
OGC (kk)	120	17	1700	46	mg C/MJ
OGC (FTIR)	160	24	1500	-	mg C/MJ
CH4 (FTIR)	30	22	350	-	mg C/MJ
C6H6 (FTIR)	20	27	210	-	mg C/MJ

Table 14 and 15 are from Heljo et al 2005^[11]. Coefficient of CO₂-ekv/CO₂ as 1.02 is used in transformation CO₂ emission factors to CO₂-ekv. factors for electricity and district heating.

Table 14. CO₂ emission factors of energy use of buildings (kg CO₂/MWh)

	Gross of building level	Dispersion	Efficiency	Efficienfy energy level
Light oil	267	-	0.85	314
Heavy oil	279	-	0.85	328
Wood	-	-	-	-
District heating
Separate production	226	20-500	-	226
Co-production	220	dispersion	-	220
Electricity production
Average	200	-	-	200
Marginal	700	700-900	-	700
or
Basic capacity	110	-	-	110
Interval capacity	450	-	-	450
Peak capacity	850	-	-	850

Table 15. CO₂-ekv emission factors of energy use of buildings (kg CO₂-ekv/MWh)

	Gross of building level	Dispersion	Efficiency	Efficienfy energy level
Light oil	267	-	0.85	314
Heavy oil	279	-	0.85	328
Wood	18	-	0.6	30
District heating
Separate production	231	20-500	-	231
Co-production	224	dispersion	-	224
Electricity production
Average	204	-	-	204
Marginal	714	700-900	-	714
or
Basic capacity	112	-	-	112
Interval capacity	459	-	-	459
Peak capacity	867	-	-	867

Dependencies

Plant/kettle type
Power output
Efficiency

Data that have another unit than mg/MJ should be changed.

e.g. t/TJ -> mg/MJ

References

[11]

Related files

[1] Karvosenoja et al. 2008 [1]

[2] ttp://www.ymparisto.fi/download.asp?contentid=3706

[3] ttp://www.vtt.fi/inf/pdf/tiedotteet/2005/T2300.pdf

[4] ttp://www.ymparisto.fi/download.asp?contentid=3706

[5] [2]

[6] ttp://tilastokeskus.fi/tup/khkinv/fi_nir_150110.pdf

[7] ttp://motiva.fi/files/209/Laskentaohje_CO2_kohde_040622.pdf

[8] ttp://motiva.fi/files/209/Laskentaohje_CO2_kohde_040622.pdf

[9] ttp://motiva.fi/files/209/Laskentaohje_CO2_kohde_040622.pdf

[10] ttp://www.uku.fi/fine/src/raportit/PUPOloppuraportti2007.pdf

[11] ttp://www.tut.fi/units/rak/rtt/tutkimus/ekorem/EKOREM_Loppuraportti_051214.pdf

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Difference between revisions of "Emission factors for burning processes"

Revision as of 13:43, 24 June 2015

Contents

Question

Answer

Rationale

Inputs

Calculations

Emission factors for heating

Other data

Dependencies

See also

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